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Demyan Prokopchuk
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Iron catalysts containing amine (imine) diphosphine P-NH-NP ligands catalyze both the asymmetric hydrogenation and asymmetric transfer hydrogenation of ketones
W Zuo, S Tauer, DE Prokopchuk, RH Morris
Organometallics 33 (20), 5791-5801, 2014
1102014
Inner-sphere activation, outer-sphere catalysis: theoretical study on the mechanism of transfer hydrogenation of ketones using iron (II) PNNP eneamido complexes
DE Prokopchuk, RH Morris
Organometallics 31 (21), 7375-7385, 2012
1072012
Catalytic N2 Reduction to Silylamines and Thermodynamics of N2 Binding at Square Planar Fe
DE Prokopchuk, ES Wiedner, ED Walter, CV Popescu, NA Piro, ...
Journal of the American Chemical Society 139 (27), 9291-9301, 2017
782017
Details of the mechanism of the asymmetric transfer hydrogenation of acetophenone using the amine (imine) diphosphine iron precatalyst: the base effect and the …
W Zuo, DE Prokopchuk, AJ Lough, RH Morris
Acs Catalysis 6 (1), 301-314, 2016
682016
Spectroscopic and DFT Study of Ferraaziridine Complexes Formed in the Transfer Hydrogenation of Acetophenone Catalyzed Using trans-[Fe (CO)(NCMe)(PPh2C6H4CH NCH2−) 2-κ4 P, N …
DE Prokopchuk, JF Sonnenberg, N Meyer, M Zimmer-De Iuliis, AJ Lough, ...
Organometallics 31 (8), 3056-3064, 2012
672012
Manganese catalyzed asymmetric transfer hydrogenation of ketones using chiral oxamide ligands
J Schneekönig, K Junge, M Beller
Synlett 30 (04), 503-507, 2019
472019
Exploring the role of pendant amines in transition metal complexes for the reduction of N2 to hydrazine and ammonia
P Bhattacharya, DE Prokopchuk, MT Mock
Coordination Chemistry Reviews 334, 67-83, 2017
452017
From pyrroles to isoindolines: Synthesis of a γ-diimine ligand for applications in palladium coordination chemistry and catalysis
JM Chitanda, DE Prokopchuk, JW Quail, SR Foley
Organometallics 27 (10), 2337-2345, 2008
402008
Asymmetric Transfer Hydrogenation of Ketones Using New Iron (II)(P‐NH‐N‐P′) Catalysts: Changing the Steric and Electronic Properties at Phosphorus P′
SAM Smith, DE Prokopchuk, RH Morris
Israel Journal of Chemistry 57 (12), 1204-1215, 2017
302017
H2 Binding, Splitting, and Net Hydrogen Atom Transfer at a Paramagnetic Iron Complex
DE Prokopchuk, GM Chambers, ED Walter, MT Mock, RM Bullock
Journal of the American Chemical Society 141 (5), 1871-1876, 2019
282019
Intramolecular C H/O H Bond Cleavage with Water and Alcohol Using a Phosphine‐Free Ruthenium Carbene NCN Pincer Complex
DE Prokopchuk, BTH Tsui, AJ Lough, RH Morris
Chemistry–A European Journal 20 (51), 16960-16968, 2014
252014
Synthesis of palladacycles employing iminoisoindolines as monoanionic bidentate ligands
JM Chitanda, DE Prokopchuk, JW Quail, SR Foley
Dalton Transactions, 6023-6029, 2008
192008
Structural properties of trans hydrido–hydroxo M (H)(OH)(NH 2 CMe 2 CMe 2 NH 2)(PPh 3) 2 (M= Ru, Os) complexes and their proton exchange behaviour with water in solution
DE Prokopchuk, A Collado, AJ Lough, RH Morris
Dalton Transactions 42 (28), 10214-10220, 2013
152013
Ligand-centered electrochemical processes enable CO 2 reduction with a nickel bis (triazapentadienyl) complex
Z Dubrawski, J Heidebrecht, BMP Lombardi, AS Hyla, J Willkomm, ...
Sustainable Energy & Fuels 3 (5), 1172-1181, 2019
122019
Alcohol-assisted base-free hydrogenation of acetophenone catalyzed by OsH(NHCMe2CMe2NH2)(PPh3)2
SE Clapham, MZD Iuliis, K Mack, DE Prokopchuk, RH Morris
Canadian Journal of Chemistry 92 (8), 731-738, 2014
112014
Phosphine-free ruthenium NCN-ligand complexes and their use in catalytic CO 2 hydrogenation
MMH Sung, DE Prokopchuk, RH Morris
Dalton Transactions 48 (44), 16569-16577, 2019
102019
From amine to ruthenaziridine to azaallyl: unusual transformation of di-(2-pyridylmethyl) amine on ruthenium
DE Prokopchuk, AJ Lough, RH Morris
Dalton Transactions 40 (40), 10603-10608, 2011
102011
A redox-active Mn (0) dicarbene metalloradical
A Karagiannis, AM Tyryshkin, RA Lalancette, DM Spasyuk, A Washington, ...
Chemical Communications 58 (93), 12963-12966, 2022
72022
Ligands for Iron‐based Homogeneous Catalysts for the Asymmetric Hydrogenation of Ketones and Imines
DE Prokopchuk, SAM Smith, RH Morris
Ligand design in metal chemistry: reactivity and catalysis, 205-236, 2016
72016
Coordination-Induced Weakening of a C(sp3)–H Bond: Homolytic and Heterolytic Bond Strength of a CH–Ni Agostic Interaction
L Lin, DM Spasyuk, RA Lalancette, DE Prokopchuk
Journal of the American Chemical Society 144 (28), 12632-12637, 2022
62022
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